Use este identificador para citar ou linkar para este item: http://hdl.handle.net/1843/43052
Tipo: Artigo de Periódico
Título: Liquid-liquid equilibria in aqueous two-phase ethanol/salt systems at different temperatures and their application to anthocyanins extraction
Autor(es): Ana Clara Rocha Caldeira
Wanderley Filho Lopes de França
Attilio Converti
William James Nogueira Lima
Fábio Coelho Sampaio
Janaína Teles de Faria
Resumo: Aqueous two-phase systems (ATPS) are formed by mixtures of chemical species that, under certain conditions, separate into two immiscible phases, with water as the major component in global terms and, at lower concentrations, polymers, salts, ionic liquids and alcohols, depending on the system type. Different parameters influence ATPS equilibrium such as temperature, alcohol carbon chain size, salt type, pH, etc. The present work aimed to obtain the binodal curves for ATPS made up of ethanol, sodium citrate/ammonium sulfate and water at different temperatures (15, 25 and 35 °C) as well as to evaluate the potential of the ethanol/ammonium sulfate system in anthocyanins partition. The results showed that the increase in temperature did not alter the biphasic region in the temperature range investigated, not influencing the formation of phases. Nonlinear equations were satisfactorily fitted to binodal curves data, except for sodium citrate-containing ATPS at 15 °C. Higher concentration of the overall mixture resulted in longer tie-line of ammonium sulphate-containing ATPS. Higher values of partition coefficient and recovery yield of Syzygium cumini fruit anthocyanins were obtained at longer tie-lines.
Assunto: Regra das fases
Equilíbrio líquido-líquido
Idioma: eng
País: Brasil
Editor: Universidade Federal de Minas Gerais
Sigla da Instituição: UFMG
Departamento: ICA - INSTITUTO DE CIÊNCIAS AGRÁRIAS
Tipo de Acesso: Acesso Aberto
Identificador DOI: 10.1590/fst.32218
URI: http://hdl.handle.net/1843/43052
Data do documento: 2019
metadata.dc.url.externa: http://dx.doi.org/10.1590/fst.32218
metadata.dc.relation.ispartof: Food Science and Technology
Aparece nas coleções:Artigo de Periódico

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