Please use this identifier to cite or link to this item: http://hdl.handle.net/1843/57704
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dc.creatorAnderson Diaspt_BR
dc.creatorRoberto Luiz Moreirapt_BR
dc.date.accessioned2023-08-10T18:33:10Z-
dc.date.available2023-08-10T18:33:10Z-
dc.date.issued2018-
dc.citation.volume49pt_BR
dc.citation.issue9pt_BR
dc.citation.spage1514pt_BR
dc.citation.epage1521pt_BR
dc.identifier.doihttps://doi.org/10.1002/jrs.5405pt_BR
dc.identifier.issn0377-0486pt_BR
dc.identifier.urihttp://hdl.handle.net/1843/57704-
dc.description.resumoSrAl2O4 materials were obtained by molten salt synthesis and sintered at high temperatures to produce a ceramic body suitable for polarization-resolved Raman spectroscopy measurements. Optimized experimental conditions were employed to study the complex vibrational spectrum of these ceramics under polarized light. A reliable set of experimental bands was obtained: 69 Raman modes were in fact observed, out of the 81 bands foreseen for the stable monoclinic polymorph of the material, from which 38 could be assigned as totally symmetric A-type modes, and 31 attributed as asymmetric B-type ones. Significant differences between experimental data and theoretical predictions indicated that additional efforts are necessary to understand these two sets of vibrational information. The knowledge of the optical phonon features reported here can help to understand the exceptional luminescence properties of SrAl2O4 in its monoclinic phase.pt_BR
dc.description.sponsorshipCNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológicopt_BR
dc.description.sponsorshipFAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas Geraispt_BR
dc.description.sponsorshipFINEP - Financiadora de Estudos e Projetos, Financiadora de Estudos e Projetospt_BR
dc.description.sponsorshipOutra Agênciapt_BR
dc.languageengpt_BR
dc.publisherUniversidade Federal de Minas Geraispt_BR
dc.publisher.countryBrasilpt_BR
dc.publisher.departmentICX - DEPARTAMENTO DE FÍSICApt_BR
dc.publisher.departmentICX - DEPARTAMENTO DE QUÍMICApt_BR
dc.publisher.initialsUFMGpt_BR
dc.relation.ispartofJournal of Raman Spectroscopypt_BR
dc.rightsAcesso Restritopt_BR
dc.subjectCeramicspt_BR
dc.subjectPhosphorspt_BR
dc.subjectPolarization-resolved Raman spectroscopypt_BR
dc.subjectSinteringpt_BR
dc.subjectStrontium monoaluminate - SrAl2O4pt_BR
dc.subject.otherMaterial cerâmicopt_BR
dc.subject.otherRaman, Espectroscopia dept_BR
dc.subject.otherSinterizaçãopt_BR
dc.subject.otherEstrônciopt_BR
dc.subject.otherMicroestruturapt_BR
dc.subject.otherLuminescênciapt_BR
dc.titlePolarization-resolved Raman modes of monoclinic SrAl2O4 ceramicspt_BR
dc.typeArtigo de Periódicopt_BR
dc.url.externahttps://analyticalsciencejournals.onlinelibrary.wiley.com/doi/10.1002/jrs.5405pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0001-7413-1087pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0001-6820-0269pt_BR
Appears in Collections:Artigo de Periódico

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