Use este identificador para citar o ir al link de este elemento: http://hdl.handle.net/1843/63147
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Campo DCValorIdioma
dc.creatorAretha Priscilla Silva Andradept_BR
dc.creatorLucas Micquéias Arantespt_BR
dc.creatorJuliana Yurie Kadoocapt_BR
dc.creatorRenato Lúcio de Carvalhopt_BR
dc.creatorÂngelo de Fátimapt_BR
dc.creatorAdão Aparecido Sabinopt_BR
dc.date.accessioned2024-01-19T17:39:59Z-
dc.date.available2024-01-19T17:39:59Z-
dc.date.issued2016-
dc.citation.volume1pt_BR
dc.citation.issue5pt_BR
dc.citation.spage886pt_BR
dc.citation.epage890pt_BR
dc.identifier.doihttps://doi.org/10.1002/slct.201600244pt_BR
dc.identifier.issn2365-6549pt_BR
dc.identifier.urihttp://hdl.handle.net/1843/63147-
dc.description.resumoThis article describes the synthesis of six palladium complexesderived from threebis-imines or their corresponding amines.These metallic complexes were evaluated as promising cata-lysts for Heck reaction. The potential of such organometalliccatalysts was investigated using the coupling between bromo-benzene and styrene as reaction model, involving evaluation ofranging bases, different solvents, reaction times and the quan-tity of palladium catalyst. Our findings indicate that the com-plexes obtained from amines are better than those fromimines. Dimethyl acetamide (DMA) and sodium carbonate werethe best solvents and bases in the Heck coupling reaction, re-spectively. In summary, these Schiff bases and correspondingamines provide an innovative opportunity to develop new cat-alytic systems for the Heck reactionpt_BR
dc.description.sponsorshipCNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológicopt_BR
dc.description.sponsorshipFAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas Geraispt_BR
dc.description.sponsorshipCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superiorpt_BR
dc.description.sponsorshipOutra Agênciapt_BR
dc.languageengpt_BR
dc.publisherUniversidade Federal de Minas Geraispt_BR
dc.publisher.countryBrasilpt_BR
dc.publisher.departmentICX - DEPARTAMENTO DE QUÍMICApt_BR
dc.publisher.initialsUFMGpt_BR
dc.relation.ispartofChemistrySelectpt_BR
dc.rightsAcesso Restritopt_BR
dc.subjectSchiff basept_BR
dc.subjectHeck reactionpt_BR
dc.subjectPalladium complexespt_BR
dc.subjectTetradentate ligandspt_BR
dc.subject.otherSchiff, Bases dept_BR
dc.subject.otherPaladiopt_BR
dc.subject.otherAminaspt_BR
dc.subject.otherCatalisept_BR
dc.subject.otherComplexos metálicospt_BR
dc.titlePalladium complexes with tetradentate schiff bases or their corresponding amines: synthesis and application in heck reactionspt_BR
dc.typeArtigo de Periódicopt_BR
dc.url.externahttps://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/slct.201600244pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-6178-4617pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0001-9767-392Xpt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-8515-9306pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0003-2344-5590pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0003-1265-7694pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-7921-3732pt_BR
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