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http://hdl.handle.net/1843/63147
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Campo DC | Valor | Idioma |
---|---|---|
dc.creator | Aretha Priscilla Silva Andrade | pt_BR |
dc.creator | Lucas Micquéias Arantes | pt_BR |
dc.creator | Juliana Yurie Kadooca | pt_BR |
dc.creator | Renato Lúcio de Carvalho | pt_BR |
dc.creator | Ângelo de Fátima | pt_BR |
dc.creator | Adão Aparecido Sabino | pt_BR |
dc.date.accessioned | 2024-01-19T17:39:59Z | - |
dc.date.available | 2024-01-19T17:39:59Z | - |
dc.date.issued | 2016 | - |
dc.citation.volume | 1 | pt_BR |
dc.citation.issue | 5 | pt_BR |
dc.citation.spage | 886 | pt_BR |
dc.citation.epage | 890 | pt_BR |
dc.identifier.doi | https://doi.org/10.1002/slct.201600244 | pt_BR |
dc.identifier.issn | 2365-6549 | pt_BR |
dc.identifier.uri | http://hdl.handle.net/1843/63147 | - |
dc.description.resumo | This article describes the synthesis of six palladium complexesderived from threebis-imines or their corresponding amines.These metallic complexes were evaluated as promising cata-lysts for Heck reaction. The potential of such organometalliccatalysts was investigated using the coupling between bromo-benzene and styrene as reaction model, involving evaluation ofranging bases, different solvents, reaction times and the quan-tity of palladium catalyst. Our findings indicate that the com-plexes obtained from amines are better than those fromimines. Dimethyl acetamide (DMA) and sodium carbonate werethe best solvents and bases in the Heck coupling reaction, re-spectively. In summary, these Schiff bases and correspondingamines provide an innovative opportunity to develop new cat-alytic systems for the Heck reaction | pt_BR |
dc.description.sponsorship | CNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico | pt_BR |
dc.description.sponsorship | FAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas Gerais | pt_BR |
dc.description.sponsorship | CAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superior | pt_BR |
dc.description.sponsorship | Outra Agência | pt_BR |
dc.language | eng | pt_BR |
dc.publisher | Universidade Federal de Minas Gerais | pt_BR |
dc.publisher.country | Brasil | pt_BR |
dc.publisher.department | ICX - DEPARTAMENTO DE QUÍMICA | pt_BR |
dc.publisher.initials | UFMG | pt_BR |
dc.relation.ispartof | ChemistrySelect | pt_BR |
dc.rights | Acesso Restrito | pt_BR |
dc.subject | Schiff base | pt_BR |
dc.subject | Heck reaction | pt_BR |
dc.subject | Palladium complexes | pt_BR |
dc.subject | Tetradentate ligands | pt_BR |
dc.subject.other | Schiff, Bases de | pt_BR |
dc.subject.other | Paladio | pt_BR |
dc.subject.other | Aminas | pt_BR |
dc.subject.other | Catalise | pt_BR |
dc.subject.other | Complexos metálicos | pt_BR |
dc.title | Palladium complexes with tetradentate schiff bases or their corresponding amines: synthesis and application in heck reactions | pt_BR |
dc.type | Artigo de Periódico | pt_BR |
dc.url.externa | https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/slct.201600244 | pt_BR |
dc.identifier.orcid | https://orcid.org/0000-0002-6178-4617 | pt_BR |
dc.identifier.orcid | https://orcid.org/0000-0001-9767-392X | pt_BR |
dc.identifier.orcid | https://orcid.org/0000-0002-8515-9306 | pt_BR |
dc.identifier.orcid | https://orcid.org/0000-0003-2344-5590 | pt_BR |
dc.identifier.orcid | https://orcid.org/0000-0003-1265-7694 | pt_BR |
dc.identifier.orcid | https://orcid.org/0000-0002-7921-3732 | pt_BR |
Aparece en las colecciones: | Artigo de Periódico |
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