1. Repositório Institucional da UFMG
  2. Publicações Científicas e Culturais
  3. Artigo de Periódico
Use este identificador para citar o ir al link de este elemento: http://hdl.handle.net/1843/68396
Registro completo de metadatos
Campo DCValorIdioma
dc.creatorIsabelle Karine Vieira Gonçalvespt_BR
dc.creatorWillian Xerxes Coelho Oliveirapt_BR
dc.creatorFilipe Barra de Almeidapt_BR
dc.creatorMaria Vanda Marinhopt_BR
dc.creatorWalace Doti do Pimpt_BR
dc.creatorPriscila Pereira Silva Caldeirapt_BR
dc.date.accessioned2024-05-16T12:13:49Z-
dc.date.available2024-05-16T12:13:49Z-
dc.date.issued2021-
dc.citation.volume198pt_BR
dc.identifier.doihttps://doi.org/10.1016/j.poly.2021.115068pt_BR
dc.identifier.issn1873-3719pt_BR
dc.identifier.urihttp://hdl.handle.net/1843/68396-
dc.description.resumoAromatic carboxylates have been vastly applied as building blocks for the assembly of robust molecularbased materials owing to their potential application in various fields. In this family, 1,3-benzenedicarboxylate (1,3-bdc), which possesses a ‘‘V”-type configuration, has been distinguished. Over the past 20 years, the number of compounds based on 1,3-bdc rapidly expanded due to its multifaceted coordination chemistry and the possibility to generate materials with diversified applications. Therefore, the main purpose of this study is to explore the structural aspects, diversity, and the factors that influence coordination modes of 1,3-bdc by comparison of a series of structurally related compounds. In this sense, we highlight some aspects that can assist in a more rational design of coordination networks based on 1,3-bdc. We also discuss the structural-spectroscopic correlation of the metal-carboxylate bonds aimed at providing support for further investigation on multifunctional materials based on 1,3-bdc, including the amorphous solids. As a direct application of this knowledge, we produced two new CuII-based compounds by the combination of 1,3-bdc and 1,10-phenanthroline (phen). We obtained a discrete complex formed by two cocrystallized mononuclear complexes, {[Cu(1,3-Hbdc)(phen)(H2O)2]ClO4 [Cu(1,3-bdc) (phen)(H2O)2] 2(H2O)} (1), and a coordination polymer, {[Cu(1,3-bdc)(phen)(H2O)] DMF}n (2), and we provided a further investigation of the nature and features of these compounds based on the discussion raised in this systematic study.pt_BR
dc.description.sponsorshipCNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológicopt_BR
dc.description.sponsorshipFAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas Geraispt_BR
dc.description.sponsorshipCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superiorpt_BR
dc.description.sponsorshipOutra Agênciapt_BR
dc.languageengpt_BR
dc.publisherUniversidade Federal de Minas Geraispt_BR
dc.publisher.countryBrasilpt_BR
dc.publisher.departmentICX - DEPARTAMENTO DE QUÍMICApt_BR
dc.publisher.initialsUFMGpt_BR
dc.relation.ispartofPolyhedronpt_BR
dc.rightsAcesso Restritopt_BR
dc.subject1,3-Benzenedicarboxylic acidpt_BR
dc.subjectIsophtalic acidpt_BR
dc.subjectCoordination polymerpt_BR
dc.subjectCoordination modespt_BR
dc.subjectStructural diversitypt_BR
dc.subjectInfrared spectroscopypt_BR
dc.subject.otherAnálise espectralpt_BR
dc.subject.otherQuímica de coordenaçãopt_BR
dc.subject.otherEspectroscopia de infravermelhopt_BR
dc.subject.otherPolimerospt_BR
dc.titleThe versatile coordination chemistry of 1,3-benzenedicarboxylate in the last 20 years: an investigation from the coordination modes to spectroscopic insightspt_BR
dc.typeArtigo de Periódicopt_BR
dc.url.externahttps://www.sciencedirect.com/science/article/pii/S0277538721000504pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0003-0722-5352pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0003-2189-9572pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-9983-3840pt_BR
Aparece en las colecciones:Artigo de Periódico

archivos asociados a este elemento:
no existem archivos asociados a este elemento.
Mostrar registro simple del elemento Visualizar estadísticas


Los elementos en el repositorio están protegidos por copyright, con todos los derechos reservados, salvo cuando es indicado lo contrario.