Please use this identifier to cite or link to this item:
http://hdl.handle.net/1843/46657| Type: | Artigo de Periódico |
| Title: | Simultaneous determination of fumonisins B1 and B2 in different types of maize by matrix solid phase dispersion and HPLC-MS/MS |
| Authors: | Gabriel Barros de Oliveira Carolyne Menezes de Castro Gomes Vieira Ricardo Mathias Orlando Adriana Ferreira Faria |
| Abstract: | This work involved the optimization and validation of a method, according to Directive 2002/657/EC and the Analytical Quality Assurance Manual of Ministério da Agricultura, Pecuária e Abastecimento, Brazil, for simultaneous extraction and determination of fumonisins B1 and B2 in maize. The extraction procedure was based on a matrix solid phase dispersion approach, the optimization of which employed a sequence of different factorial designs. A liquid chromatography-tandem mass spectrometry method was developed for determining these analytes using the selected reaction monitoring mode. The optimized method employed only 1 g of silica gel for dispersion and elution with 70% ammonium formate aqueous buffer (50 mmol L−1, pH 9), representing a simple, cheap and chemically friendly sample preparation method. Trueness (recoveries: 86–106%), precision (RSD ≤19%), decision limits, detection capabilities and measurement uncertainties were calculated for the validated method. The method scope was expanded to popcorn kernels, white maize kernels and yellow maize grits. |
| Subject: | Milho Milho de pipoca Cromatografia líquida Espectrometria de massa Extração (Química) Silica gel Preparação de amostra (Química) Micotoxinas Alimentos Análise |
| language: | eng |
| metadata.dc.publisher.country: | Brasil |
| Publisher: | Universidade Federal de Minas Gerais |
| Publisher Initials: | UFMG |
| metadata.dc.publisher.department: | ICX - DEPARTAMENTO DE QUÍMICA |
| Rights: | Acesso Aberto |
| metadata.dc.identifier.doi: | https://doi.org/10.1016/j.foodchem.2017.04.091 |
| URI: | http://hdl.handle.net/1843/46657 |
| Issue Date: | 2017 |
| metadata.dc.url.externa: | https://www.sciencedirect.com/science/article/pii/S0308814617306623#! |
| metadata.dc.relation.ispartof: | Food Chemistry |
| Appears in Collections: | Artigo de Periódico |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Simultaneous determination of fumonisins B1 and B2 in different types.pdf | 747.31 kB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.