Please use this identifier to cite or link to this item: http://hdl.handle.net/1843/55191
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dc.creatorCristiane Almeida Scaldaferript_BR
dc.creatorVânya Márcia Duarte Pasapt_BR
dc.date.accessioned2023-06-21T17:58:35Z-
dc.date.available2023-06-21T17:58:35Z-
dc.date.issued2019-
dc.citation.volume370pt_BR
dc.citation.spage98pt_BR
dc.citation.epage109pt_BR
dc.identifier.doihttps://doi.org/10.1016/j.cej.2019.03.063pt_BR
dc.identifier.issn1873-3212pt_BR
dc.identifier.urihttp://hdl.handle.net/1843/55191-
dc.description.resumoBiomass conversion into liquid products of interest for the fuel formulations has been draw remarkable attention to reducing the environmental pollution in the world. Biofuels play an important key to mitigating climate changes from the development of sustainable processes. Drop-in biofuels are oxygen-free biofuels composed by liquid hydrocarbons obtained from renewable sources. In the present work, a screening with different catalysts was performed for soybean oil deoxygenation. The niobium phosphate catalyst (NbOPO4) showed a great performance in the production of drop-in fuels in different conditions of reaction. The hydrocarbon yields are in the range of 76–90% (wt%). The redox and acid properties of NbOPO4 led to the simultaneous formation of bio-hydrocarbons, such as linear (38%) and branched alkanes (14%), cycloalkanes (1%), olefins (1%) and aromatics (36%) compounds. NbOPO4 exhibits higher selectivity to bio-jet fuel (58%), followed by green diesel (37%) and biogasoline (21%). This sustainable route to produce bio-hydrocarbons brings a process using N2 gas instead of H2 gas. This is an innovative, sustainable, efficient, safe and low-cost technology with great potential for industry applicationpt_BR
dc.description.sponsorshipCNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológicopt_BR
dc.languageengpt_BR
dc.publisherUniversidade Federal de Minas Geraispt_BR
dc.publisher.countryBrasilpt_BR
dc.publisher.departmentICX - DEPARTAMENTO DE QUÍMICApt_BR
dc.publisher.initialsUFMGpt_BR
dc.relation.ispartofChemical Engineering Journal-
dc.rightsAcesso Restritopt_BR
dc.subjectBio-jet fuelpt_BR
dc.subjectGreen dieselpt_BR
dc.subjectDrop-in biofuelspt_BR
dc.subjectNiobium phosphate catalystpt_BR
dc.subjectDeoxygenationpt_BR
dc.subjectUpgrading reactionspt_BR
dc.subject.otherBiocombustíveispt_BR
dc.subject.otherBiodieselpt_BR
dc.subject.otherÓleo de sojapt_BR
dc.subject.otherCompostos de nióbiopt_BR
dc.subject.otherCatálisept_BR
dc.titleHydrogen-free process to convert lipids into bio-jet fuel and green diesel over niobium phosphate catalyst in one-steppt_BR
dc.typeArtigo de Periódicopt_BR
dc.url.externahttps://www.sciencedirect.com/science/article/pii/S1385894719305339pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-1610-8118pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-2510-3845pt_BR
Appears in Collections:Artigo de Periódico

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