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Please use this identifier to cite or link to this item: http://hdl.handle.net/1843/55197
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dc.creatorCristiane Almeida Scaldaferript_BR
dc.creatorVânya Márcia Duarte Pasapt_BR
dc.date.accessioned2023-06-21T18:57:09Z-
dc.date.available2023-06-21T18:57:09Z-
dc.date.issued2019-
dc.citation.volume245pt_BR
dc.citation.spage458pt_BR
dc.citation.epage466pt_BR
dc.identifier.doihttps://doi.org/10.1016/j.fuel.2019.01.179pt_BR
dc.identifier.issn1873-7153pt_BR
dc.identifier.urihttp://hdl.handle.net/1843/55197-
dc.description.resumoDrop-in biofuels are non-oxygenated biofuels composed by biohydrocarbons produced from different biomass. These drop-in biofuels (biogasoline, bio jet-fuel and green diesel) show a great importance due to their properties similar to those observed for fossil fuels. Lipids are one of the most important raw material used for deoxygenation reactions over special catalysts. In this work, niobium phosphate was investigated as catalyst in the production of drop-in biofuels from soybean oil, using mild experimental conditions. The performance of niobium phosphate was evaluated under different reaction time (3–5 h), catalyst amount (0–25%) and temperature (300–350 °C), using 10 bar H2. The composition of the liquid products was determined by gas chromatography coupled with mass spectrometry, and characterized by infrared spectroscopy. The optimization process led to high yields of hydrocarbons in the range of C9–C17. About 62% of bio-jet fuel, 40% of green diesel, and 18% of gasoline range hydrocarbons were obtained in a single reaction step. Their composition included mainly linear and branched alkanes as well as aromatics compounds. The pathways for the involved reactions are discussed.pt_BR
dc.description.sponsorshipCNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológicopt_BR
dc.languageengpt_BR
dc.publisherUniversidade Federal de Minas Geraispt_BR
dc.publisher.countryBrasilpt_BR
dc.publisher.departmentICX - DEPARTAMENTO DE QUÍMICApt_BR
dc.publisher.initialsUFMGpt_BR
dc.relation.ispartofFuel-
dc.rightsAcesso Restritopt_BR
dc.subjectNiobium phosphate catalystpt_BR
dc.subjectDeoxygenationpt_BR
dc.subjectIsomerizationpt_BR
dc.subjectBio-jet fuelpt_BR
dc.subjectDrop-in biofuelspt_BR
dc.subject.otherBiocombustíveispt_BR
dc.subject.otherBiodieselpt_BR
dc.subject.otherCompostos de nióbiopt_BR
dc.subject.otherCatálisept_BR
dc.subject.otherAviões - Combustíveispt_BR
dc.subject.otherÓleo de sojapt_BR
dc.titleProduction of jet fuel and green diesel range biohydrocarbons by hydroprocessing of soybean oil over niobium phosphate catalystpt_BR
dc.typeArtigo de Periódicopt_BR
dc.url.externahttps://www.sciencedirect.com/science/article/pii/S0016236119301796pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-1610-8118pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-2510-3845pt_BR
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