Please use this identifier to cite or link to this item: http://hdl.handle.net/1843/55363
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dc.creatorMaria Flávia Rodrigues Starling Araújopt_BR
dc.creatorPoliana Lima Cardosopt_BR
dc.creatorGiulia Luiza Rindoni Souzapt_BR
dc.creatorClaudia Cristina Cardoso da Silvapt_BR
dc.creatorVânya Márcia Duarte Pasapt_BR
dc.date.accessioned2023-06-26T18:04:12Z-
dc.date.available2023-06-26T18:04:12Z-
dc.date.issued2021-
dc.citation.volume413pt_BR
dc.identifier.doihttps://doi.org/10.1016/j.cej.2020.127432pt_BR
dc.identifier.issn1873-3212pt_BR
dc.identifier.urihttp://hdl.handle.net/1843/55363-
dc.description.resumoSugarcane bagasse is an abundant residue from the ethanol/sugar industries and its liquefaction can be a low-cost process for the production of liquid biofuels. However, the resulting biocrude has high acidity, which requires an upgrading before being used. In this study, ethanol and fusel oil, which is the heavy residue of ethanol distillation made up of higher alcohols, were used as solvents for the liquefaction of bagasse. The 1:10 biomass:solvent ratio mixture was used at 300 °C for 30 min and (10 bar) N2 atmosphere. A mixture of both solvents was also tested to make a comparative study. The process with ethanol showed 72% bagasse conversion, but the best result showed 91% with fusel oil, producing a low biochar content (9%). After the distillation of the liquid product, a biocrude with high combustion heat (30.6 MJ.kg−¹) and rich in esters was obtained. The results of GC/MS revealed the greater presence of esters with substituted isoamyl groups (51.2%) and, to a lesser extent, phenolic compounds (2.5%). The biochar has a higher heating value of 30 MJ.kg−¹ and special thermal stability, suitable for application as a solid fuel. The biocrude was mixed with marine diesel (5%) and the properties of the mixture were evaluated, without relevant modifications. This innovative process showed the use of two residues, bagasse, and fusel oil, to produce a biofuel to be used with different types of diesel, with economic and environmental gains in a cycle economy for the ethanol industry.pt_BR
dc.description.sponsorshipCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superiorpt_BR
dc.languageengpt_BR
dc.publisherUniversidade Federal de Minas Geraispt_BR
dc.publisher.countryBrasilpt_BR
dc.publisher.departmentICX - DEPARTAMENTO DE QUÍMICApt_BR
dc.publisher.initialsUFMGpt_BR
dc.relation.ispartofChemical Engineering Journalpt_BR
dc.rightsAcesso Restritopt_BR
dc.subjectThermal liquefactionpt_BR
dc.subjectFusel oilpt_BR
dc.subjectDistilled biocrudept_BR
dc.subjectMaritime dieselpt_BR
dc.subjectAlternative fuelspt_BR
dc.subject.otherConversão de biomassapt_BR
dc.subject.otherBiocombustíveispt_BR
dc.subject.otherBagaço de canapt_BR
dc.subject.otherAlcoolpt_BR
dc.subject.otherEsterificação (Química)pt_BR
dc.subject.otherCombustíveis líquidospt_BR
dc.titleSimultaneous thermal liquefaction of sugarcane bagasse and esterification with ethanol and fusel oil: one-step process for biofuel productionpt_BR
dc.typeArtigo de Periódicopt_BR
dc.url.externahttps://www.sciencedirect.com/science/article/pii/S1385894720335567pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-7333-1228pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-6487-9304pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0001-5940-1042pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-2510-3845pt_BR
Appears in Collections:Artigo de Periódico

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