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http://hdl.handle.net/1843/56370| Type: | Artigo de Periódico |
| Title: | A periodic walk through a series of first-row, oxido-bridged, heterodimetallic molecules: synthesis and structure |
| Authors: | Eric Michael Goggins Travis T. Lekich Walter Warren Weare Roger D. Sommer Marcos Antônio Ribeiro Carlos Basílio Pinheiro |
| Abstract: | A series of heterodimetallic molecules, centered around an LTi=O→M2+L′ (M = Mn, Fe, Co, Ni, Cu, Zn) core, are described. Each of these complexes are structurally similar, with L = tmtaa and L′ = Py5Me2. The Ti=O→M linkage is slightly bent, varying from 157° (Mn) to 170° (Zn), with bond lengths typical of a dative bond between the Ti=O group and the M2+ center. The relative strength of the heterodimetallic linkage is correlated with the Lewis acidity of the M2+ precursor, with Mn2+ showing the strongest interaction and Ni2+ the weakest. By varying the metal identity the electrochemical properties of the molecules can be tuned, along with the M3+/2+ redox couple. This series of complexes provide a platform for studying structure/function relationships in heterodimetallic molecules linked through a single atom. For instance, spectroscopic features such as IR stretching frequencies can be roughly correlated with structural features such as bond lengths and angles. |
| Subject: | Complexos metálicos |
| language: | eng |
| metadata.dc.publisher.country: | Brasil |
| Publisher: | Universidade Federal de Minas Gerais |
| Publisher Initials: | UFMG |
| metadata.dc.publisher.department: | ICX - DEPARTAMENTO DE FÍSICA |
| Rights: | Acesso Restrito |
| metadata.dc.identifier.doi: | https://doi.org/10.1002/ejic.201501325 |
| URI: | http://hdl.handle.net/1843/56370 |
| Issue Date: | 2016 |
| metadata.dc.url.externa: | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201501325 |
| metadata.dc.relation.ispartof: | European Journal of Inorganic Chemistry |
| Appears in Collections: | Artigo de Periódico |
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