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Please use this identifier to cite or link to this item: http://hdl.handle.net/1843/56872
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dc.creatorIara Maria Landre Rosapt_BR
dc.creatorAna C. Z. dos Santospt_BR
dc.creatorLuana Aparecida dos Reis Giustopt_BR
dc.creatorCarlos Basílio Pinheiropt_BR
dc.creatorAntônio Carlos Doriguettopt_BR
dc.date.accessioned2023-07-24T12:53:02Z-
dc.date.available2023-07-24T12:53:02Z-
dc.date.issued2017-
dc.citation.volume28pt_BR
dc.citation.issue11pt_BR
dc.citation.spage2073pt_BR
dc.citation.epage2083pt_BR
dc.identifier.doihttps://doi.org/10.21577/0103-5053.20170052pt_BR
dc.identifier.issn1678-4790pt_BR
dc.identifier.urihttp://hdl.handle.net/1843/56872-
dc.description.resumoA same coordination polymer [Zn(aip)(DMSO)] (aip: 5-aminoisophthalate and DMSO: dimethylsulfoxide) was synthesized using the same reactants (ZnSO4, aip and H2O/DMSO) but in different conditions, in which the stoichiometry (1:1-4:1 metal:ligand ratio), temperature (70 and 100 °C) and synthetic method (liquid-liquid diffusion, solvothermal and conventional with stirring) varied. A liquid assisted mechanochemical approach using ZnO as ZnII source instead ZnSO4, but keeping DMSO as milling liquid, also resulted in the same compound. This new coordination polymer was investigated using single-crystal X-ray diffraction technique, revealing a two-dimensional honeycomb-type network formation. The crystal structure was compared with either similar or isostructural compounds reported in the literature. Our studies show that the synthetic method and other synthetic variables do not affect the formation of [Zn(aip)(DMSO)] coordination polymers and probe the high stability (thermodynamic and kinetic) and structural invariance of this structure.pt_BR
dc.description.sponsorshipCNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológicopt_BR
dc.description.sponsorshipFAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas Geraispt_BR
dc.description.sponsorshipCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superiorpt_BR
dc.description.sponsorshipFINEP - Financiadora de Estudos e Projetos, Financiadora de Estudos e Projetospt_BR
dc.format.mimetypepdfpt_BR
dc.languageengpt_BR
dc.publisherUniversidade Federal de Minas Geraispt_BR
dc.publisher.countryBrasilpt_BR
dc.publisher.departmentICX - DEPARTAMENTO DE FÍSICApt_BR
dc.publisher.initialsUFMGpt_BR
dc.relation.ispartofJournal of the Brazilian Chemical Society-
dc.rightsAcesso Abertopt_BR
dc.subjectCoordination polymerpt_BR
dc.subjectZinc aminoisophthalatept_BR
dc.subjectNetwork stabilitypt_BR
dc.subjectX-ray diffractionpt_BR
dc.subject.otherPolímerospt_BR
dc.subject.otherZincopt_BR
dc.subject.otherRaios Xpt_BR
dc.subject.otherDifraçãopt_BR
dc.titleStructural invariance of a Zn II coordination polymer with 5-aminoisophthalic acid under different synthetic conditionspt_BR
dc.typeArtigo de Periódicopt_BR
dc.url.externahttps://www.scielo.br/j/jbchs/a/yJsBKwKYCWz4yTs7cP3JBwQ/abstract/?lang=enpt_BR
dc.identifier.orcidhttps://orcid.org/0000-0003-3846-8656pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0003-0178-3660pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-8674-1779pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-2726-1265pt_BR
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