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http://hdl.handle.net/1843/57521| Type: | Artigo de Periódico |
| Title: | Obtaining Mn-Co alloys in AISI 430 steel from lithium-ion battery recycling: application in SOFC interconnectors |
| Authors: | Sicele Luciana Abreu Gonçalves Eric Marsalha Garcia Hosane Aparecida Tarôco Tulio Matencio |
| Abstract: | The recycling of exhausted lithium-ion batteries from mobile phones originate five solutions with different Co and Mn proportions that were used as electrolytic solutions to obtain Mn-Co spinel coatings on the surface of AISI430 stainless steel. The coatings are intended to contain chromium volatility in the working conditions of Solid Oxide Fuel Cells (SOFC) metallic interconnectors. Potentiostatic electrodeposition was the technique used to obtain Mn-Co coatings from low concentration electrolytes at pH = 3.0 and potential applied −1.3 V. Charge efficiency data were used for sample optimization. Three optimized samples were subjected to oxidation heat treatment at 800 °C for 300 h and then characterized by XRD, SEM and EDS. The results showed that the addition of manganese ions instead of cobalt ions in the electrolytic bath produces more stable and well-distributed deposits as the ratio of the two ions becomes equal in the electrolytic bath. Thin, homogeneous and stable spinel coatings (Mn, Co)3O4 2.8 μm and 3.9 μm thick were able to block chromium volatility when exposed to SOFC operating temperature. |
| Subject: | Eletroquímica Baterias de lítio Aço inoxidável Ligas de manganês Ligas de cobalto Cromo Baterias - Reaproveitamento Células à combustível Raios X - Difração Eletrodeposição Voltametria Microscopia eletrônica de varredura Solução eletrolítica |
| language: | eng |
| metadata.dc.publisher.country: | Brasil |
| Publisher: | Universidade Federal de Minas Gerais |
| Publisher Initials: | UFMG |
| metadata.dc.publisher.department: | ENG - DEPARTAMENTO DE ENGENHARIA QUÍMICA ICX - DEPARTAMENTO DE QUÍMICA |
| Rights: | Acesso Aberto |
| metadata.dc.identifier.doi: | https://doi.org/10.3390/chemengineering4010010 |
| URI: | http://hdl.handle.net/1843/57521 |
| Issue Date: | 2020 |
| metadata.dc.url.externa: | https://www.mdpi.com/2305-7084/4/1/10 |
| metadata.dc.relation.ispartof: | ChemEngineering |
| Appears in Collections: | Artigo de Periódico |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Obtaining mn-co alloys in aisi 430 steel from lithium-ion battery recycling application in sofc interconnectors.pdf | 1.04 MB | Adobe PDF | View/Open |
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