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Please use this identifier to cite or link to this item: http://hdl.handle.net/1843/59440
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dc.creatorFernando Machado dos Santospt_BR
dc.creatorMeiry Edivirges Alvarengapt_BR
dc.creatorAna Karoline Silva Mendanha Valdopt_BR
dc.creatorRenato Rabelo de Souza Filhopt_BR
dc.creatorDanielle Cangussu de Castro Gomespt_BR
dc.creatorÂngelo de Fátimapt_BR
dc.creatorThiago Vinicius Costa Larapt_BR
dc.creatorCleiton Moreira da Silvapt_BR
dc.creatorThiago Teixeira Tassopt_BR
dc.creatorJoão Honorato de Araujo Netopt_BR
dc.creatorAlzir Azevedo Batistapt_BR
dc.creatorAlejandro Pedro Ayalapt_BR
dc.creatorJavier Alcides Ellenapt_BR
dc.creatorVinicius Ferraz Guimarãespt_BR
dc.creatorCecilia Maria Alves de Oliveirapt_BR
dc.creatorLidya Cardozo da Silvapt_BR
dc.creatorBoniek Gontijo Vazpt_BR
dc.creatorFelipe Terra Martinspt_BR
dc.date.accessioned2023-10-16T13:53:52Z-
dc.date.available2023-10-16T13:53:52Z-
dc.date.issued2020-
dc.citation.volume56pt_BR
dc.citation.issue95pt_BR
dc.citation.spage15024pt_BR
dc.citation.epage15027pt_BR
dc.identifier.doihttps://doi.org/10.1039/D0CC07043Bpt_BR
dc.identifier.issn1364-548Xpt_BR
dc.identifier.urihttp://hdl.handle.net/1843/59440-
dc.description.resumoHere we discovered an unprecedented giant octahedral coordination compound bearing 16 Zn2+, 12 Na+, 8 O2−, 4 OH−, 13 H2O and 6 L4− ligands [L4− = fully deprotonated tetra(carboxymethoxy)calix[4]arene]. Its structure was elucidated by single-crystal X-ray diffraction, wavelength-dispersive X-ray spectroscopy and MALDI-TOF mass spectrometry. This compound, Zn8Na6L6⊃Zn8Na6O8(OH)4(H2O)13 (external⊃internal), has eight tetrahedral zinc ions forming the coordination vertices of an outermost cube where carboxylate groups from the sodium calixarenes are anchored. Its core consists of eight Zn2+, six Na+, eight O2−, and four OH− distributed over three layers, besides thirteen coordinated H2O molecules.pt_BR
dc.languageengpt_BR
dc.publisherUniversidade Federal de Minas Geraispt_BR
dc.publisher.countryBrasilpt_BR
dc.publisher.departmentICX - DEPARTAMENTO DE QUÍMICApt_BR
dc.publisher.initialsUFMGpt_BR
dc.relation.ispartofChemical Communicationspt_BR
dc.rightsAcesso Restritopt_BR
dc.subjectOctahedral coordination compoundpt_BR
dc.subjectCalixarenept_BR
dc.subject.otherCalixarenospt_BR
dc.subject.otherCompostos de coordenaçãopt_BR
dc.subject.otherCompostos complexospt_BR
dc.subject.otherQuímica orgânicapt_BR
dc.subject.otherQuímica inorgânicapt_BR
dc.titleA giant hybrid organic-inorganic octahedron from a narrow rim carboxylate calixarenept_BR
dc.typeArtigo de Periódicopt_BR
dc.url.externahttps://pubs.rsc.org/en/content/articlelanding/2020/CC/D0CC07043Bpt_BR
dc.identifier.orcidhttps://orcid.org/0000-0001-9034-8796pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-3686-7779pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-0967-2300pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0001-8442-4334pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0003-2344-5590pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0001-9913-8971pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0001-9362-9227pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-1127-6083pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-9247-6780pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-0676-3098pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0003-3339-5363pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0002-0058-1744pt_BR
dc.identifier.orcidhttps://orcid.org/0000-0003-1197-4284pt_BR
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