Please use this identifier to cite or link to this item: http://hdl.handle.net/1843/60734
Type: Artigo de Periódico
Title: Role of Nb on the phase stability and morphology of Ti–Ni–Cu–Nb alloys
Authors: Jéssica Dornelas Silva
Gisele Fernandes Chaves Macieira
Dilson Silva Dos Santos
Leandro de Arruda Santos
Vicente Tadeu Lopes Buono
Abstract: Ti52-xNi38Cu10Nbx alloys with Nb additions of x = 4, 6, and 10 at.% were produced through arc melting. The phase constitution and morphology were evaluated through X-ray diffraction, microstructural analyses (scanning electron microscopy/energy-dispersive X-ray spectroscopy), and thermodynamic calculations (ThermoCalc). The as-cast alloys exhibited a TiNi matrix, β-Nb/TiNi eutectic, and Ti2Ni precipitates. Under equilibrium conditions, TiNi and a small fraction of β-Nb were expected. Increasing the Nb content resulted in a higher β-Nb volume fraction, development of different morphologies for Ti2Ni precipitates, and formation of Ti particles. The Scheil calculator and virtual composition of the liquid were used to simulate the effect of chemical segregation during solidification. We demonstrated that the metastable phases formed during solidification and the Nb content played a vital role in the solidification sequence, phase distribution, and morphology of the alloy.
Subject: Termodinâmica
Engenharia metalúrgica
language: eng
metadata.dc.publisher.country: Brasil
Publisher: Universidade Federal de Minas Gerais
Publisher Initials: UFMG
metadata.dc.publisher.department: ENG - DEPARTAMENTO DE ENGENHARIA METALÚRGICA
ENGENHARIA - ESCOLA DE ENGENHARIA
Rights: Acesso Aberto
metadata.dc.identifier.doi: https://doi.org/10.1016/j.jmrt.2022.07.146
URI: http://hdl.handle.net/1843/60734
Issue Date: 2022
metadata.dc.url.externa: https://www.sciencedirect.com/science/article/pii/S2238785422012066?via%3Dihub
metadata.dc.relation.ispartof: Journal of Materials Research and Technology
Appears in Collections:Artigo de Periódico

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