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http://hdl.handle.net/1843/61391| Type: | Artigo de Periódico |
| Title: | Synthesis of SmLuO3 and EuLuO3 interlanthanides from hydrothermally-derived nanostructured precursors |
| Authors: | Júlia Cristina Soares Kisla Prislen Félix Siqueira Roberto Luiz Moreira Anderson Dias |
| Abstract: | Phase-pure cubic SmLuO3 and EuLuO3 interlanthanides were synthesized for the first time from nanostructured hydrothermally-derived precursors. LuO(OH), Sm(OH)3 and Eu(OH)3 materials were firstly obtained by hydrothermal synthesis at 250 °C for 24 h. X-ray diffraction, micro-Raman spectroscopy, scanning and transmission electron microscopies were employed to investigate the thermal behavior of the mixed systems Sm(OH)3–LuO(OH) and Eu(OH)3–LuO(OH), up to 1600 °C. It was observed that the precursors were converted to lanthanide oxides in the temperature range 800–1200 °C, followed by chemical reactions that allowed the production of a mixture of monoclinic and cubic SmLuO3 or EuLuO3 materials at 1400 °C. Phase-pure cubic (space group, #206) interlanthanides were produced at 1600 °C, as corroborated by micro-Raman scattering probing the phonon modes, which were determined and assigned. The results showed that both systems could be promising materials for optical applications. |
| Subject: | Compostos de lantanio Compostos de metais de terras raras Alteração hidrotermal Raman, Espectroscopia de Hidróxidos Raios X - Difração Microscopia eletrônica Interação eletron-fonon |
| language: | eng |
| metadata.dc.publisher.country: | Brasil |
| Publisher: | Universidade Federal de Minas Gerais |
| Publisher Initials: | UFMG |
| metadata.dc.publisher.department: | ICX - DEPARTAMENTO DE FÍSICA ICX - DEPARTAMENTO DE QUÍMICA |
| Rights: | Acesso Aberto |
| metadata.dc.identifier.doi: | https://doi.org/10.1016/j.arabjc.2016.03.010 |
| URI: | http://hdl.handle.net/1843/61391 |
| Issue Date: | 2019 |
| metadata.dc.url.externa: | https://www.sciencedirect.com/science/article/pii/S1878535216300247 |
| metadata.dc.relation.ispartof: | Arabian Journal of Chemistry |
| Appears in Collections: | Artigo de Periódico |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| Synthesis of SmLuO3 and EuLuO3 interlanthanides from hydrothermally-derived nanostructured precursors.pdf | 1.67 MB | Adobe PDF | View/Open |
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