Please use this identifier to cite or link to this item: http://hdl.handle.net/1843/64141
Type: Artigo de Periódico
Title: Graphene nanoencapsulation action at an air/lipid interface
Authors: Gustavo Arrighi Ferrari
Rodrigo Gribel Lacerda
Helio Chacham
Alan Barros de Oliveira
Matheus Josué de Souza Matos
Ronaldo Junio Campos Batista
Leonel Muniz Meireles
Ana Paula Moreira Barboza
Ive Silvestre de Almeida
Bernardo Ruegger Almeida Neves
Abstract: In the present work, we apply a microfluidic channel platform to study mechanical and adhesion properties of suspended graphene in contact with oleic acid (a lipid). In the platform, one side of the suspended graphene, atop a window in a fluidic channel, is placed in contact with the lipid, and the mechanical response of graphene is experimentally accessed with an atomic force microscope probe. We observe a strong effect arising from the presence of oleic acid: the probe undergoes a large jump-to-contact effect, being pulled and partially encapsulated by graphene, in a phagocytosis-like phenomenon, until it penetrates 0.2 µm into graphene. In contrast, such encapsulation effect is negligible in the absence of oleic acid in the channel, with probe penetration of less than 0.02 µm. The lipid-induced encapsulation effect is observed to occur concurrently with graphene delamination from the window walls. Molecular dynamics simulations and continuum mechanics analytical modeling are also performed, the latter allowing quantitative fittings to the experiments.
Subject: Grafeno
Lipídios
language: eng
metadata.dc.publisher.country: Brasil
Publisher: Universidade Federal de Minas Gerais
Publisher Initials: UFMG
metadata.dc.publisher.department: ICX - DEPARTAMENTO DE FÍSICA
Rights: Acesso Restrito
metadata.dc.identifier.doi: https://doi.org/10.1007/s10853-022-07030-0
URI: http://hdl.handle.net/1843/64141
Issue Date: 2022
metadata.dc.url.externa: https://link.springer.com/article/10.1007/s10853-022-07030-0
metadata.dc.relation.ispartof: Journal of Materials Science
Appears in Collections:Artigo de Periódico

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