Fragmenting nanoputians: capturing admiration to the rationality, predictability, and beauty of ion chemistry in mass spectrometry

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dc.creatorAdao Aparecido Sabino
dc.creatorStephanie H. Chanteau
dc.creatorJoão Henrique Astolfi Ferreira
dc.creatorAlicia Camacho
dc.creatorThiago da Cruz Canevari
dc.creatorJames Mitchell Tour
dc.creatorMarcos Nogueira Eberlin
dc.date.accessioned2023-10-09T21:07:36Z
dc.date.accessioned2025-09-09T00:11:39Z
dc.date.available2023-10-09T21:07:36Z
dc.date.issued2022
dc.description.sponsorshipCNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico
dc.description.sponsorshipCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
dc.description.sponsorshipOutra Agência
dc.identifier.doihttps://doi.org/10.1002/jms.4881
dc.identifier.issn1076-5174
dc.identifier.urihttps://hdl.handle.net/1843/59305
dc.languageeng
dc.publisherUniversidade Federal de Minas Gerais
dc.relation.ispartofJournal of Mass Spectrometry
dc.rightsAcesso Restrito
dc.subjectEspectrometria de massa
dc.subjectMoléculas
dc.subjectNanotecnologia
dc.subjectDissociação
dc.subjectEducação
dc.subjectQuímica
dc.subject.otherIon chemistry
dc.subject.otherEducation
dc.subject.otherTandem mass spectrometry
dc.subject.otherFragmentation
dc.titleFragmenting nanoputians: capturing admiration to the rationality, predictability, and beauty of ion chemistry in mass spectrometry
dc.typeArtigo de periódico
local.citation.epage7
local.citation.issue9
local.citation.spage1
local.citation.volume57
local.description.resumoThe fragmentation chemistry of the protonated and ionized nanoPutian 1 has been studied in the gas phase via electrospray ionization and tandem mass spectrometry. A direct analogy was observed between the fragmentation chemistry of this fascinating “humanoid molecule” and “cleavages” at certain parts of the human body. We argue that such direct analogy and illustrative schemes for the fragmentation of molecular ions of 1 offer a ludic and efficient tool to teach and capture attention to ion chemistry in mass spectrometry. Using the changes in mass for the two heavier nanoPutians with different head styles but the same body design, the analogy has also been used to predict mass spectra. The concepts of isotopic labelling and dissociation thresholds have also been illustrated. For many years, the approach has been successfully used by one of us in classes and lectures, mainly when presenting ion chemistry to students and audiences from fields other than Chemistry, most particularly from Biology, Medicine, and Forensic Chemistry.
local.identifier.orcidhttps://orcid.org/0000-0003-1265-7694
local.identifier.orcidhttps://orcid.org/0000-0002-4336-8097
local.identifier.orcidhttps://orcid.org/0000-0002-8479-9328
local.identifier.orcidhttps://orcid.org/0000-0003-4868-0618
local.publisher.countryBrasil
local.publisher.departmentICX - DEPARTAMENTO DE QUÍMICA
local.publisher.initialsUFMG
local.url.externahttps://analyticalsciencejournals.onlinelibrary.wiley.com/doi/10.1002/jms.4881

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