Use of water: white spirit microemulsion to clean a white monochromatic painting by Gilda Azevedo

dc.creatorJoão Cura D'ars de Figueiredo Junior
dc.creatorMárcia Georgina de Assis
dc.creatorMaria Alice Honório Sanna Castello Branco
dc.date.accessioned2025-09-04T13:30:10Z
dc.date.accessioned2025-09-08T23:54:06Z
dc.date.available2025-09-04T13:30:10Z
dc.date.issued2024
dc.format.mimetypepdf
dc.identifier.doihttp://doi.org/10.1016/j.culher.2024.08.013
dc.identifier.issn1296-2074
dc.identifier.urihttps://hdl.handle.net/1843/84845
dc.languageeng
dc.publisherUniversidade Federal de Minas Gerais
dc.rightsAcesso Aberto
dc.subjectPintura - Conservação e restauração
dc.subjectArte - Conservação e restauração
dc.subject.otherCleaning
dc.subject.other20th century oil painting
dc.subject.otherMicroemulsion
dc.subject.otherConductivity measurements
dc.subject.otherPercolation
dc.titleUse of water: white spirit microemulsion to clean a white monochromatic painting by Gilda Azevedo
dc.typeArtigo de periódico
local.citation.epage18
local.citation.spage12
local.citation.volume70
local.description.resumoCleaning a painting is a process that requires knowledge of its materiality, integrity, and solvent systems. Aqueous solvent systems are a sustainable alternative, but their use must consider the potential harm that can arise in the process- such as swelling and leaching of layers underlying the dirt. Modern oil paintings made from the twentieth century onwards may be sensitive to aqueous solvents and suffer such damage. In this work, the cleaning of a white monochromatic oil painting by artist Gilda Azevedo was carried out with a microemulsified system of water in white-spirit using Tween 80 and ethanol as surfac- tant and cosurfactant, respectively. The microemulsified system and emulsions are the result of a ternary pseudodiagram where water, white-spirit, and surfactant/cosurfactant are carefully rationed. The emul- sions obtained were characterized by measurements of conductivity and Dynamic Light Scattering. The artwork was examined by infrared absorption spectroscopy and X-ray fluorescence spectroscopy. Cleaning tests were firstly performed with emulsions and microemulsion and the removal of pigments was qual- itatively analyzed by X-ray fluorescence spectroscopy. It was observed that the microemulsified system was an efficient cleaner while causing less removal of pigments compared to emulsified systems and, thus, chosen for cleaning. This cleaning efficiency was attributed to the use of water-white-spirit mixes capable of interacting with hydrophobic and hydrophilic substances in dirt. The lower pigment removal was ascribed to the dynamic percolation system and the nanometric size of the microemulsions.
local.identifier.orcidhttps://orcid.org/0000-0002-4901-1005
local.identifier.orcidhttps://orcid.org/0000-0002-8458-6699
local.publisher.countryBrasil
local.publisher.departmentEBA - DEPARTAMENTO DE ARTES PLÁSTICAS
local.publisher.initialsUFMG

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