Structural invariance of a Zn II coordination polymer with 5-aminoisophthalic acid under different synthetic conditions

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dc.creatorIara Maria Landre Rosa
dc.creatorAna C. Z. dos Santos
dc.creatorLuana Aparecida dos Reis Giusto
dc.creatorCarlos Basílio Pinheiro
dc.creatorAntônio Carlos Doriguetto
dc.date.accessioned2023-07-24T12:53:02Z
dc.date.accessioned2025-09-09T00:02:54Z
dc.date.available2023-07-24T12:53:02Z
dc.date.issued2017
dc.description.sponsorshipCNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico
dc.description.sponsorshipFAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas Gerais
dc.description.sponsorshipCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
dc.description.sponsorshipFINEP - Financiadora de Estudos e Projetos, Financiadora de Estudos e Projetos
dc.format.mimetypepdf
dc.identifier.doihttps://doi.org/10.21577/0103-5053.20170052
dc.identifier.issn1678-4790
dc.identifier.urihttps://hdl.handle.net/1843/56872
dc.languageeng
dc.publisherUniversidade Federal de Minas Gerais
dc.relation.ispartofJournal of the Brazilian Chemical Society
dc.rightsAcesso Aberto
dc.subjectPolímeros
dc.subjectZinco
dc.subjectRaios X
dc.subjectDifração
dc.subject.otherCoordination polymer
dc.subject.otherZinc aminoisophthalate
dc.subject.otherNetwork stability
dc.subject.otherX-ray diffraction
dc.titleStructural invariance of a Zn II coordination polymer with 5-aminoisophthalic acid under different synthetic conditions
dc.typeArtigo de periódico
local.citation.epage2083
local.citation.issue11
local.citation.spage2073
local.citation.volume28
local.description.resumoA same coordination polymer [Zn(aip)(DMSO)] (aip: 5-aminoisophthalate and DMSO: dimethylsulfoxide) was synthesized using the same reactants (ZnSO4, aip and H2O/DMSO) but in different conditions, in which the stoichiometry (1:1-4:1 metal:ligand ratio), temperature (70 and 100 °C) and synthetic method (liquid-liquid diffusion, solvothermal and conventional with stirring) varied. A liquid assisted mechanochemical approach using ZnO as ZnII source instead ZnSO4, but keeping DMSO as milling liquid, also resulted in the same compound. This new coordination polymer was investigated using single-crystal X-ray diffraction technique, revealing a two-dimensional honeycomb-type network formation. The crystal structure was compared with either similar or isostructural compounds reported in the literature. Our studies show that the synthetic method and other synthetic variables do not affect the formation of [Zn(aip)(DMSO)] coordination polymers and probe the high stability (thermodynamic and kinetic) and structural invariance of this structure.
local.identifier.orcidhttps://orcid.org/0000-0003-3846-8656
local.identifier.orcidhttps://orcid.org/0000-0003-0178-3660
local.identifier.orcidhttps://orcid.org/0000-0002-8674-1779
local.identifier.orcidhttps://orcid.org/0000-0002-2726-1265
local.publisher.countryBrasil
local.publisher.departmentICX - DEPARTAMENTO DE FÍSICA
local.publisher.initialsUFMG
local.url.externahttps://www.scielo.br/j/jbchs/a/yJsBKwKYCWz4yTs7cP3JBwQ/abstract/?lang=en

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