Solvent-free hydroboration of alkenes and alkynes catalyzed by rhodium-ruthenium nanoparticles on carbon nanotubes

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dc.creatorMateus P. Nunes
dc.creatorDhanaji V. Jawale
dc.creatorFábio Godoy Delolo
dc.creatorMaria Helena de Araujo
dc.creatorEdmond Gravel
dc.creatorEric Doris
dc.creatorEufrânio N. da Silva Júnior
dc.date.accessioned2026-01-07T19:57:20Z
dc.date.issued2023-02-07
dc.identifier.doihttps://doi.org/10.1039/D2CC06864H
dc.identifier.issn1359-7345
dc.identifier.urihttps://hdl.handle.net/1843/1321
dc.languageeng
dc.publisherUniversidade Federal de Minas Gerais
dc.relation.ispartofChemical Communications
dc.rightsAcesso aberto
dc.rightsCC0 1.0 Universalen
dc.rights.urihttp://creativecommons.org/publicdomain/zero/1.0/
dc.subjectNanopartículas
dc.subjectCatalisadores
dc.subjectInibidores químicos
dc.titleSolvent-free hydroboration of alkenes and alkynes catalyzed by rhodium-ruthenium nanoparticles on carbon nanotubes
dc.typeArtigo de periódico
local.citation.epage2766
local.citation.issue19
local.citation.spage2763
local.citation.volume59
local.description.resumoA heterogeneous catalyst consisting of bimetallic rhodiumruthenium particles immobilized on carbon nanotubes was used in the hydroboration reaction and proved highly effective for a variety of alkenes and alkynes. The reactions were carried out with low catalytic loadings (0.04 mol%), under solvent-free conditions, and at room temperature. In addition, to demonstrate its recyclability, the catalyst was recovered by a simple centrifugation process and reused over 5 consecutive cycles without losing any activity.
local.identifier.orcidhttps://orcid.org/0000-0001-7968-9506
local.identifier.orcidhttps://orcid.org/0000-0001-6077-1016
local.identifier.orcidhttps://orcid.org/0000-0003-1318-602X
local.identifier.orcidhttps://orcid.org/0000-0003-1281-5453
local.publisher.countryBrasil
local.publisher.departmentICX - DEPARTAMENTO DE QUÍMICA
local.publisher.initialsUFMG
local.subject.cnpqCIENCIAS EXATAS E DA TERRA::QUIMICA
local.url.externahttps://pubs.rsc.org/en/content/articlelanding/2023/cc/d2cc06864h

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