A fast and low-cost approach for the discrimination of commercial aged cachaças using synchronous fluorescence spectroscopy and multivariate classification
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Universidade Federal de Minas Gerais
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Artigo de periódico
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Resumo
Cachaça is the distilled beverage typical of Brazil and can be subjected to the aging process in wooden barrels. In addition to oak barrels, cachaça is also aged in barrels of different Brazilian native woods, resulting in a wide variety of its sensory characteristics. In this work, 172 cachaças aged in bálsamo, jequitibá, oak, and umburana barrels were analyzed by synchronous fluorescence spectroscopy and by the classification methods of principal component analysis and partial least squares discriminant analysis. Spectra were preprocessed by the first derivative by Savitzky–Golay smoothing, using a filter width and polynomial order determined through face-centered central composite designs. Multivariate analysis was realized using the spectra recorded at different wavelength differences, and models were compared by the classification errors in the test sets.
Abstract
Assunto
Envelhecimento, Bebidas destiladas, Método estatistico, Fluorimetria, Madeira, Cachaça, Espectroscopia de fluorescência, Análise discriminante, Mínimos quadrados
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Aging process, Distilled beverages, PCA, PLS-DA, Spectrofluorimetry, Wood
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https://onlinelibrary.wiley.com/doi/10.1002/jsfa.11857