Continuous flow dynamic kinetic resolution of rac-1-phenylethanol using single packed-bed containing immobilized CAL-B lipase and VOSO4 as racemization catalyst

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dc.creatorRodrigo Octavio Mendonça Alves de Souza
dc.creatorAmanda Silva de Miranda
dc.creatorRaquel A. C. Leão
dc.creatorStefania de Souza
dc.creatorFernanda Cabella Dias
dc.creatorMarcus Vinicius Mattos Silva
dc.date.accessioned2022-11-10T18:26:24Z
dc.date.accessioned2025-09-08T23:03:14Z
dc.date.available2022-11-10T18:26:24Z
dc.date.issued2017
dc.description.sponsorshipCNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico
dc.description.sponsorshipCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
dc.description.sponsorshipFAPERJ - Fundação Carlos Chagas Filho de Amparo à Pesquisa do Estado do Rio de Janeiro
dc.identifier.doihttps://doi.org/10.1039/C7RE00003K
dc.identifier.issn20589883
dc.identifier.urihttps://hdl.handle.net/1843/47137
dc.languageeng
dc.publisherUniversidade Federal de Minas Gerais
dc.relation.ispartofReaction Chemistry & Engineering
dc.rightsAcesso Restrito
dc.subjectSíntese orgânica
dc.subjectExtração por solventes
dc.subjectHidrólise
dc.subjectCromatografia líquida
dc.subjectRacemização
dc.subjectCandida
dc.subjectSíntese assimétrica
dc.subject.otherAsymmetric catalytic synthesis
dc.subject.otherRac-1-phenylethanol
dc.subject.otherDynamic kinetic resolution
dc.subject.otherCandida antarctica lipase B (CAL-B)
dc.subject.otherChemoenzymatic DKR
dc.subject.otherRacemization
dc.subject.other(R)-1-phenylethyl decanoate
dc.subject.otherAcyl donors
dc.titleContinuous flow dynamic kinetic resolution of rac-1-phenylethanol using single packed-bed containing immobilized CAL-B lipase and VOSO4 as racemization catalyst
dc.typeArtigo de periódico
local.citation.epage381
local.citation.spage375
local.citation.volume2
local.description.resumoHerein, we report a method for the continuous flow DKR of rac-1-phenylethanol catalyzed by CAL-B and VOSO4, using a single packed-bed containing both catalysts. Taking advantage of continuous flow techniques to circumvent compatibility issues, the DKR of rac-1-phenylethanol could be performed continuously to give enantiopure (R)-esters with excellent conversions and high productivities.
local.identifier.orcidhttps://orcid.org/0000-0002-6422-4025
local.identifier.orcidhttps://orcid.org/0000-0002-8887-2772
local.identifier.orcidhttps://orcid.org/0000-0002-6387-3963
local.identifier.orcidhttps://orcid.org/0000-0001-8908-4412
local.publisher.countryBrasil
local.publisher.departmentICX - DEPARTAMENTO DE QUÍMICA
local.publisher.initialsUFMG
local.url.externahttps://pubs.rsc.org/en/content/articlelanding/2017/re/c7re00003k#!

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