Palladium complexes with tetradentate schiff bases or their corresponding amines: synthesis and application in heck reactions

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dc.creatorAretha Priscilla Silva Andrade
dc.creatorLucas Micquéias Arantes
dc.creatorJuliana Yurie Kadooca
dc.creatorRenato Lúcio de Carvalho
dc.creatorÂngelo de Fátima
dc.creatorAdão Aparecido Sabino
dc.date.accessioned2024-01-19T17:39:59Z
dc.date.accessioned2025-09-09T00:20:56Z
dc.date.available2024-01-19T17:39:59Z
dc.date.issued2016
dc.description.sponsorshipCNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico
dc.description.sponsorshipFAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas Gerais
dc.description.sponsorshipCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
dc.description.sponsorshipOutra Agência
dc.identifier.doihttps://doi.org/10.1002/slct.201600244
dc.identifier.issn2365-6549
dc.identifier.urihttps://hdl.handle.net/1843/63147
dc.languageeng
dc.publisherUniversidade Federal de Minas Gerais
dc.relation.ispartofChemistrySelect
dc.rightsAcesso Restrito
dc.subjectSchiff, Bases de
dc.subjectPaladio
dc.subjectAminas
dc.subjectCatalise
dc.subjectComplexos metálicos
dc.subject.otherSchiff base
dc.subject.otherHeck reaction
dc.subject.otherPalladium complexes
dc.subject.otherTetradentate ligands
dc.titlePalladium complexes with tetradentate schiff bases or their corresponding amines: synthesis and application in heck reactions
dc.typeArtigo de periódico
local.citation.epage890
local.citation.issue5
local.citation.spage886
local.citation.volume1
local.description.resumoThis article describes the synthesis of six palladium complexesderived from threebis-imines or their corresponding amines.These metallic complexes were evaluated as promising cata-lysts for Heck reaction. The potential of such organometalliccatalysts was investigated using the coupling between bromo-benzene and styrene as reaction model, involving evaluation ofranging bases, different solvents, reaction times and the quan-tity of palladium catalyst. Our findings indicate that the com-plexes obtained from amines are better than those fromimines. Dimethyl acetamide (DMA) and sodium carbonate werethe best solvents and bases in the Heck coupling reaction, re-spectively. In summary, these Schiff bases and correspondingamines provide an innovative opportunity to develop new cat-alytic systems for the Heck reaction
local.identifier.orcidhttps://orcid.org/0000-0002-6178-4617
local.identifier.orcidhttps://orcid.org/0000-0001-9767-392X
local.identifier.orcidhttps://orcid.org/0000-0002-8515-9306
local.identifier.orcidhttps://orcid.org/0000-0003-2344-5590
local.identifier.orcidhttps://orcid.org/0000-0003-1265-7694
local.identifier.orcidhttps://orcid.org/0000-0002-7921-3732
local.publisher.countryBrasil
local.publisher.departmentICX - DEPARTAMENTO DE QUÍMICA
local.publisher.initialsUFMG
local.url.externahttps://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/slct.201600244

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