Solvent-free hydroboration of alkenes and alkynes catalyzed by rhodium-ruthenium nanoparticles on carbon nanotubes

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dc.creatorMateus Nunes
dc.creatorDhanaji Jawale
dc.creatorFábio Delolo
dc.creatorMaria Helena de Araujo Benvenutti
dc.creatorEdmond Gravel
dc.creatorEric Doris
dc.creatorEufrânio da Silva Júnior
dc.date.accessioned2025-01-24T21:35:52Z
dc.date.accessioned2025-09-08T23:17:33Z
dc.date.available2025-01-24T21:35:52Z
dc.date.issued2023-02-07
dc.format.mimetypepdf
dc.identifier.doihttps://10.1039/d2cc06864h
dc.identifier.issn1364-548X
dc.identifier.urihttps://hdl.handle.net/1843/79483
dc.languageeng
dc.publisherUniversidade Federal de Minas Gerais
dc.relation.ispartofChemical Communications
dc.rightsAcesso Aberto
dc.subjectCatálise heterogênea
dc.subjectQuímica
dc.subjectTestes químicos e reagentes
dc.titleSolvent-free hydroboration of alkenes and alkynes catalyzed by rhodium-ruthenium nanoparticles on carbon nanotubes
dc.typeArtigo de periódico
local.citation.epage2766
local.citation.issue19
local.citation.spage2763
local.citation.volume59
local.description.resumoA heterogeneous catalyst consisting of bimetallic rhodium-ruthenium particles immobilized on carbon nanotubes was used in the hydroboration reaction and proved highly effective for a variety of alkenes and alkynes. The reactions were carried out with low catalytic loadings (0.04 mol%), under solvent-free conditions, and at room temperature. In addition, to demonstrate its recyclability, the catalyst was recovered by a simple centrifugation process and reused over 5 consecutive cycles without losing any activity.
local.identifier.orcidhttps://orcid.org/0000-0001-7968-9506
local.identifier.orcidhttps://orcid.org/0000-0001-6077-1016
local.identifier.orcidhttps://orcid.org/0000-0003-1318-602X
local.identifier.orcidhttps://orcid.org/0000-0003-1281-5453
local.publisher.countryBrasil
local.publisher.departmentICX - DEPARTAMENTO DE QUÍMICA
local.publisher.initialsUFMG
local.url.externahttps://pubs.rsc.org/en/content/articlelanding/2023/cc/d2cc06864h

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