All-perylene-derivative for white light emitting diodes
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Universidade Federal de Minas Gerais
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Artigo de periódico
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Membros da banca
Resumo
An organic-based bright white light emitting compound, namely Tb(H3PTC)3 [H 4 PTC = perylene-
3,4,9,10-tetracarboxylic acid], able to be used as part of a white diode and as a part of a RGB system that can withstand high temperatures (B700 K), is developed using perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA) and terbium(III ) nitrate pentahydrate as precursors by hydrothermal synthesis. Using
PTCDA as the red emitter and the new derivative of it, Tb(H3PTC)3, as the blue-green emitter, along with a common deep blue LED can form a RGB system for display technologies, around room temperature. Temperature-dependent photoluminescence properties of the Tb(H3PTC)3 compound are
also investigated for the involved excitonic-emission processes and the respective recombination lifetimes. The terbium(III ) complex was prepared using a procedure that is reproducible, easily modifiable, inexpensive, and environmentally friendly, opening new pathways for its large-scale applications. Unlike PTCDA, Tb(H3 PTC)3 has been shown to be soluble in N-methyl-2-pyrrolidone (NMP) as well as in dilute aqueous solutions of this organic solvent in a straightforward procedure. The light emission properties
are intimately correlated with the molecular structure and electronic properties of Tb(H3 PTC)3
elucidated by experimental results of X-ray Absorption Near Edge Spectroscopy (XANES), Extended X-ray Absorption Fine Structure (EXAFS) and Density Functional Theory (DFT) calculations. A bright fluorescence yield is attained with a small amount of material either in solution or in solid form showing its potential to be used in state-of-the-art organic optoelectronic devices.
Abstract
Assunto
Fotoluminescência, Diodos emissores de luz
Palavras-chave
Photoluminescence, White light emitting diodes
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Endereço externo
https://pubs.rsc.org/en/content/articlelanding/2020/cp/d0cp02718a