Simultaneous determination of a polychlorinated dibenzo-p-dioxin and dibenzo-p-furan in environmental water bydispersive liquid-liquid microextraction (DLLME) and amodified QuEChERS procedure with high-performance liquidchromatography - diode array detection (HPLC-DAD)

Página do item simplificado
dc.creatorLázaro Chaves Sicupira
dc.creatorLucas Victor Pereira de Freitas
dc.creatorGevany Paulino de Pinho
dc.creatorFlaviano Oliveira Silvério
dc.date.accessioned2024-09-16T13:58:18Z
dc.date.accessioned2025-09-08T23:08:02Z
dc.date.available2024-09-16T13:58:18Z
dc.date.issued2023-01-16
dc.description.sponsorshipCNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico
dc.description.sponsorshipFAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas Gerais
dc.description.sponsorshipCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
dc.identifier.doihttps://doi.org/10.1080/00032719.2023.2166521
dc.identifier.issn1532-236X
dc.identifier.urihttps://hdl.handle.net/1843/76477
dc.languageeng
dc.publisherUniversidade Federal de Minas Gerais
dc.relation.ispartofAnalytical Letters
dc.rightsAcesso Restrito
dc.subjectResíduos orgânicos
dc.subjectPoluentes
dc.subjectPoluentes orgânicos aquáticos
dc.titleSimultaneous determination of a polychlorinated dibenzo-p-dioxin and dibenzo-p-furan in environmental water bydispersive liquid-liquid microextraction (DLLME) and amodified QuEChERS procedure with high-performance liquidchromatography - diode array detection (HPLC-DAD)
dc.typeArtigo de periódico
local.citation.epage2328
local.citation.issue14
local.citation.spage2309
local.citation.volume56
local.description.resumoPolychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) are persistent organic pollutants frequently detected in air, soil, and water. Thus, monitoring these compounds in environmental compartments is fundamental to identifying potential risks to human health. However, studies of analytical methods for PCDD/Fs extraction in water are still limited. Therefore, this study aimed to optimize and validate a dispersive liquid-liquid microextraction (DLLME) and QuEChERS method combined with high-performance liquid chromatography – diode array detection (HPLC-DAD) to determine 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD) and 2,3,7,8-tetrachlorodibenzofuran (2,3,7,8-TCDF) in water samples. The proposed methods were optimized to achieve higher recovery rates for PCDD/Fs extraction. DLLME and QuEChERS combined with HPLC-DAD were validated according to SANTE guidelines to ensure reliability and applicability. The recoveries of both methods ranged from 93.5 to 105.5%, and relative standard deviations were less than 12%. The analytical validation certified that the proposed methods were selective, precise, accurate, and linear, with limits of quantification ranging from 2.4 to 5.3 μg L−1. These results suggested the feasibility of DLLME and modified QuEChERS combined with HPLC-DAD as simple, inexpensive, and environmental-friendly approaches for monitoring PCDD/F in aqueous samples.
local.publisher.countryBrasil
local.publisher.departmentICA - INSTITUTO DE CIÊNCIAS AGRÁRIAS
local.publisher.initialsUFMG
local.url.externahttps://www.tandfonline.com/doi/full/10.1080/00032719.2023.2166521

Arquivos

Licença do pacote

Agora exibindo 1 - 1 de 1
Imagem de Miniatura
Nome:
License.txt
Tamanho:
1.99 KB
Formato:
Plain Text
Descrição:
Baixar

Coleções

Artigo de Periódico

Logo UFMG