The versatile coordination chemistry of 1,3-benzenedicarboxylate in the last 20 years: an investigation from the coordination modes to spectroscopic insights

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dc.creatorIsabelle Karine Vieira Gonçalves
dc.creatorWillian Xerxes Coelho Oliveira
dc.creatorFilipe Barra de Almeida
dc.creatorMaria Vanda Marinho
dc.creatorWalace Doti do Pim
dc.creatorPriscila Pereira Silva Caldeira
dc.date.accessioned2024-05-16T12:13:49Z
dc.date.accessioned2025-09-09T00:55:50Z
dc.date.available2024-05-16T12:13:49Z
dc.date.issued2021
dc.description.sponsorshipCNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico
dc.description.sponsorshipFAPEMIG - Fundação de Amparo à Pesquisa do Estado de Minas Gerais
dc.description.sponsorshipCAPES - Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
dc.description.sponsorshipOutra Agência
dc.identifier.doihttps://doi.org/10.1016/j.poly.2021.115068
dc.identifier.issn1873-3719
dc.identifier.urihttps://hdl.handle.net/1843/68396
dc.languageeng
dc.publisherUniversidade Federal de Minas Gerais
dc.relation.ispartofPolyhedron
dc.rightsAcesso Restrito
dc.subjectAnálise espectral
dc.subjectQuímica de coordenação
dc.subjectEspectroscopia de infravermelho
dc.subjectPolimeros
dc.subject.other1,3-Benzenedicarboxylic acid
dc.subject.otherIsophtalic acid
dc.subject.otherCoordination polymer
dc.subject.otherCoordination modes
dc.subject.otherStructural diversity
dc.subject.otherInfrared spectroscopy
dc.titleThe versatile coordination chemistry of 1,3-benzenedicarboxylate in the last 20 years: an investigation from the coordination modes to spectroscopic insights
dc.typeArtigo de periódico
local.citation.volume198
local.description.resumoAromatic carboxylates have been vastly applied as building blocks for the assembly of robust molecularbased materials owing to their potential application in various fields. In this family, 1,3-benzenedicarboxylate (1,3-bdc), which possesses a ‘‘V”-type configuration, has been distinguished. Over the past 20 years, the number of compounds based on 1,3-bdc rapidly expanded due to its multifaceted coordination chemistry and the possibility to generate materials with diversified applications. Therefore, the main purpose of this study is to explore the structural aspects, diversity, and the factors that influence coordination modes of 1,3-bdc by comparison of a series of structurally related compounds. In this sense, we highlight some aspects that can assist in a more rational design of coordination networks based on 1,3-bdc. We also discuss the structural-spectroscopic correlation of the metal-carboxylate bonds aimed at providing support for further investigation on multifunctional materials based on 1,3-bdc, including the amorphous solids. As a direct application of this knowledge, we produced two new CuII-based compounds by the combination of 1,3-bdc and 1,10-phenanthroline (phen). We obtained a discrete complex formed by two cocrystallized mononuclear complexes, {[Cu(1,3-Hbdc)(phen)(H2O)2]ClO4 [Cu(1,3-bdc) (phen)(H2O)2] 2(H2O)} (1), and a coordination polymer, {[Cu(1,3-bdc)(phen)(H2O)] DMF}n (2), and we provided a further investigation of the nature and features of these compounds based on the discussion raised in this systematic study.
local.identifier.orcidhttps://orcid.org/0000-0003-0722-5352
local.identifier.orcidhttps://orcid.org/0000-0003-2189-9572
local.identifier.orcidhttps://orcid.org/0000-0002-9983-3840
local.publisher.countryBrasil
local.publisher.departmentICX - DEPARTAMENTO DE QUÍMICA
local.publisher.initialsUFMG
local.url.externahttps://www.sciencedirect.com/science/article/pii/S0277538721000504

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