Optical nanoantennas for tip-enhanced Raman spectroscopy

dc.creatorThiago de Lourenço e Vasconcelos
dc.creatorBráulio Soares Archanjo
dc.creatorBruno Santos de Oliveira
dc.creatorWilliam F. Silva
dc.creatorRafael Silva Alencar
dc.creatorCassiano Rabelo e Silva
dc.creatorCarlos Alberto Achete
dc.creatorAdo Jorio de Vasconcelos
dc.creatorLuiz Gustavo de Oliveira Lopes Cançado
dc.date.accessioned2022-10-25T17:22:20Z
dc.date.accessioned2025-09-08T23:56:59Z
dc.date.available2022-10-25T17:22:20Z
dc.date.issued2020-07-10
dc.description.sponsorshipCNPq - Conselho Nacional de Desenvolvimento Científico e Tecnológico
dc.description.sponsorshipFINEP - Financiadora de Estudos e Projetos, Financiadora de Estudos e Projetos
dc.description.sponsorshipFAPERJ - Fundação Carlos Chagas Filho de Amparo à Pesquisa do Estado do Rio de Janeiro
dc.identifier.doihttps://doi.org/10.1109/JSTQE.2020.3008526
dc.identifier.issn15584542
dc.identifier.urihttps://hdl.handle.net/1843/46597
dc.languageeng
dc.publisherUniversidade Federal de Minas Gerais
dc.relation.ispartofIEEE Journal of Selected Topics in Quantum Electronics
dc.rightsAcesso Restrito
dc.subjectNanotecnologia
dc.subjectEspectroscopia de Raman
dc.subjectGrafeno
dc.subject.otherTERS
dc.subject.otherPlasmon resonance
dc.subject.otherOptical nanoantennas
dc.subject.otherGraphene
dc.subject.otherNanopattern
dc.titleOptical nanoantennas for tip-enhanced Raman spectroscopy
dc.typeArtigo de periódico
local.citation.epage4600411 - 11
local.citation.issue1
local.citation.spage4600411 - 1
local.citation.volume27
local.description.resumoThe role of plasmon resonance on the optical efficiency of nanoantennas for tip-enhanced Raman spectroscopy (TERS) is reviewed. Technical details on surface plasmon polaritons (SPP), localized surface plasmon resonance (LSPR), and the plasmon gap mode are provided. Nanotechnology engineering is necessary to adequate the nanoantenna’s size, shape and composition to match resonance conditions with the exciting radiation source. Computational simulation guides the development of new types of plasmonic nanoantennas with different materials and morphologies, specially designed to reach target applications. An overview on a recently developed nanoantenna composed by a truncated micropyramidal body with a nanopyramid end is presented. The characteristic length L of the nanopyramid tip is dimensioned to fine-tune LSPR modes, giving rise to the so-called plasmon-tunable tip pyramid (PTTP). The plasmonic properties of this type of probe were investigated by electron energy loss spectroscopy and computational simulations, reveling that PTTPs act as monopole nanoantennas. TERS results obtained with the PTTPs demonstrate the achievement of unprecedent levels of field enhancement mediated by LSPR with excellent reproducibility rate.
local.identifier.orcidhttps://orcid.org/0000-0003-0195-444X
local.identifier.orcidhttps://orcid.org/0000-0001-8145-7712
local.identifier.orcidhttps://orcid.org/0000-0002-5201-0791
local.identifier.orcidhttps://orcid.org/0000-0002-9992-7564
local.identifier.orcidhttps://orcid.org/0000-0003-0488-2242
local.identifier.orcidhttps://orcid.org/0000-0002-5978-2735
local.identifier.orcidhttps://orcid.org/0000-0003-0816-0888
local.publisher.countryBrasil
local.publisher.departmentICX - DEPARTAMENTO DE FÍSICA
local.publisher.initialsUFMG
local.url.externahttps://ieeexplore.ieee.org/document/9138720

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