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Type:	Artigo de Periódico
Title:	Disentangling contributions of point and line defects in the Raman spectra of graphene-related materials
Authors:	Luiz Gustavo de Oliveira Lopes Cançado Ado Jorio de Vasconcelos Mateus Gomes da Silva Erlon Henrique Martins Ferreira Ferdinand Hof Katerina Kampioti Kai Huang Alain Pénicaud Carlos Alberto Achete Rodrigo Barbosa Capaz
Abstract:	The transition from graphene to a fully disordered sp2 carbon material can be idealized by either cutting graphene into smaller and smaller pieces, or adding more and more point defects. In other words, from the dimensionality standpoint, defects in two-dimensional (2D) systems can be either one- (1D) or zero-dimensional (0D). From an application point of view, both in terms of bottom-up as well as top-down approaches, the discrimination between these two structural disorder in two-dimensional systems is urgently desired. In graphene, both types of defects produce changes in the Raman spectrum, but identifying separately the contribution from each defect-type has not yet been achieved. Here we show that a diagram can be built for disentangling contributions of pointlike and line-like defects to the Raman spectra of graphene-related materials embracing, from the topology point of view, all possible structures from perfect to fully disordered sp2 bonded carbons. Two sets of graphene-related samples, produced by well-established protocols that generate either 0D or 1D defects in a controlled way, are analysed with our model and used to parameterize the limiting values of the phase space. We then discuss the limitations and apply our new methodology to analyse the structure of two-dimensional nanocarbons generated from renewable gas, used to produce inks and conducting coatings.
Subject:	Espectroscopia de Raman Defeitos pontuais
language:	eng
metadata.dc.publisher.country:	Brasil
Publisher:	Universidade Federal de Minas Gerais
Publisher Initials:	UFMG
metadata.dc.publisher.department:	ICX - DEPARTAMENTO DE FÍSICA
Rights:	Acesso Aberto
metadata.dc.identifier.doi:	https://doi.org/10.1088/2053-1583/aa5e77
URI:	http://hdl.handle.net/1843/42523
Issue Date:	24-Feb-2017
metadata.dc.url.externa:	https://iopscience.iop.org/article/10.1088/2053-1583/aa5e77
metadata.dc.relation.ispartof:	2D Materials
Appears in Collections:	Artigo de Periódico

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