B – C – N diamondol-like compounds: stability trends and electronic properties

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Universidade Federal de Minas Gerais

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Artigo de periódico

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In this work we apply first principles calculations to investigate the stability trends of mixed boron, nitrogen and carbon diamondol-like compounds. Several distinct geometric models are tested by varying the stoichiometry and position of boron and nitrogen dopants. We verify the special stability of a complete boron nitride compound – the bonitrol –, and we show that carbon substitutions in the bonitrol structure may also lead to stable systems. The electronic characterization of the resulting compounds indicates a rich phenomenology, with metallic, semimetallic, half-metallic and semiconducting behaviors.

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Grafeno, Nanoestrutura

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Diamane, Diamondol, 2D materials, Nanostructures, BCN compounds

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https://www.sciencedirect.com/science/article/pii/S0927025622004566

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